渣油催化裂化催化劑DYC-01
RFCC Catalyst DYC-01
渣油催化裂化催化劑DYC-01是山東多友科技有限公司利用專有DYC催化劑技術平臺針對M100、M180、焦化蠟油等劣質催化原料專門開發(fā)的一種渣油轉化催化劑,該種催化劑具有孔道階梯分布合理、比表面積大、分子篩活性組分高、穩(wěn)定性好、抗堿性氮和重金屬污染能力強等特點,特別適用于加工劣質催化原料,增加液收。
RFCC catalyst DYC-01 is specially developed by Shandong Duo You Technology Co. Ltd. with its proprietary DYC technology platform for M100, M180, CGO (coker gas oil) and other heavy feedstocks, featured with graded distribution of pore structures, higher specific area, higher content of zeolite, good hydrothermal stability, benefits on contaminant metals resistance and basic nitrogen poisoning tolerance, particularly applicable for heavy feedstock to enhance yield of valuable products.
1、DYC-01催化劑的物化性能指標
1、Physical-chemical Specification of DYC-01 Catalyst.
表1 DYC-01催化劑的物化性能質量指標
Table 1 Physical-chemical Specification of DYC-01 Catalyst
*催化劑經800oC、100%水蒸氣條件下老化;標準輕柴油進料,460℃反應。
*Catalyst steamed under 800oC/100% steam;standard light diesel feed,cracking temperature 460 ℃。
2、抗重金屬污染性能
2、Contaminant Metals Resistance
圖1 金屬污染對DYC-01與對比渣油催化劑活性的影響
Figure 1 Effect of Contaminant Metals Levels of DYC-01 and Competitive RFCC Catalyst
圖1 結果表明,與國內外廣泛使用的渣油催化劑相比,DYC-01催化劑在抗重金屬污染方面具有明顯的優(yōu)勢。
The results in figure 1 showed that DYC-01 catalyst had significant advantages on contaminant metals resistance compared with widely-used competitive RFCC catalyst.
3、ACE催化裂化性能評價
3. Catalytic Cracking Performance of DYC- 01 Catalyst on ACE Unit
采用M100作為評價原料,在ACE反應評價裝置上對DYC-01催化劑的催化性能進行了評價。表2給出了催化裂化反應評價結果。
The catalytic performance evaluation of DYC-01 catalyst was carried out with M100 feed in ACE catalytic cracking testing unit. Results are listed in Table 2.
表2 ACE催化裂化評價結果
Table 2 Results of DYC-01 Catalyst on ACE Unit
*催化劑經100%水蒸汽,17小時,800℃老化處理;
*Catalyst steamed at 800℃/100% steam/17h;
從表2結果可以看出:在相同反應評價條件下,DYC-01催化劑的轉化率比對比渣油催化劑高2.09個百分點,焦炭產率相當,汽油+柴油收率和總液收分別提高1.4個百分點,液化氣+汽油+柴油收率和總液收分別提高1.85個百分點,油漿下降1.60個百分點。充分顯示了DYC-01催化劑優(yōu)良的渣油催化裂化和抗重金屬污染的性能。
Table 2 shows that under the same reaction conditions, compared with competitive RFCC catalyst, heavy oil conversion for DYC-01 catalyst was higher by 2.09%, gasoline+LCO yield and LPG+gasoline+LCO Yield is higher by 1.24% and 2.05%, respectively, meanwhile, coke yield remains the same, bottoms yield decreases by 1.60%. The results fully show that DYC-01 catalyst has better performance on both resid cracking and contaminant metals tolerance.
上述結果表明:DYC-01催化劑不僅具有很好的物化性能指標,而且具有很好的催化裂解高金屬和高堿性氮含量的劣質渣油的能力。我們相信,選用DYC-01催化劑,必將會提高重油催化裂化裝置的經濟效益。
Based on these results, the following observations can be made: DYC-01 catalyst combines good physical-chemical properties with high cracking conversion potential of resid containing high levels of metals and basic nitrogen. We believe that the application of DYC-01 catalyst will definitely enhance economic potential of RFCC unit.
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